The English side claimed an emphatic 7-0 win at home against Spartak Moscow to win Group E and ensure that Seville - who drew 1-1 at Maribor - would join them.
Jose Mourinho's men, who returned to the Champions League by winning last season's Europa League, beat FC Basel 3-0 at home and CSKA Moscow 4-1 in Moscow before back-to-back victories over Benfica 1-0 and 2-0 respectively.
It is the first time in the history of the Champions League that a country has had five teams in the last-16 stage of the competition.
"Well if you see the teams that you could face even being first, was hard but it's true that being first you play the second leg at home".
The Premier League has set a new record as all five of its representatives in this season's Champions League qualified for the knockout stages.
Roma knew they would go through from Group C with a win, which they got, although they could only edge out Qarabag of Azerbaijan 1-0 at the Stadio Olimpico with a Diego Perotti effort in the second half.
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Bayern Munich still finished second in Group B with 15 points, the same as PSG but the goal differential is what proved to make the difference in the final standings.
For the Round of 16 draw, the group winners will be placed in Pot 1, and group runners up will be in Pot 2.
There are only four Round of 16 spots left to play for on Wednesday night ahead of the draw on December 10 in Nyon.
The eight group winners will be seeded and will be away in the first-leg matches, which are scheduled for 13/14 and 20/21 February.
PARIS: Manchester United and Juventus were among the sides to clinch a place in the last 16 of the Champions League on Tuesday, while Bayern Munich gained a measure of revenge over Paris Saint-Germain.