The attack took place outside Saint-Charles station shortly after 11am on Sunday morning.
Two of them - aged 20 and 21- were reportedly hit in the face and rushed to hospital with burns, while the attacker was arrested by police. She says all four of the tourists, who are in their 20s, have been hospitalized, two of them for shock.
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Four female United States tourists have been attacked with acid in Marseille's main train station.
The four tourists, in their early twenties, were travelling between Marseilles and Paris when a 41-year-old man sprayed them with hydrochloric acid, according to reports. Police do not believe the attack is terror related. Paris prosecutor Francois Molins told reporters the two suspects "were getting ready to carry out an imminent, violent action" on French territory.